Acetic acid 50% – Identification of Product
Chemical Code: RLS-SOL-A10
Chemical Name: Acetic Acid 50%
Solution Chemical Grade:
Chemical Formula: No Data Available
Chemical Weight: 60.05 g/mol
CAS No: 64-19-7
Chemical Synonyms: Acetic Acid solution 50%
Acetic acid 50% – Hazards Identification
REACH No: No Data Available
Signal Word: Danger
Supplemental Hazard Information:
Additional Hazard Information: This substance/mixture contains no components considered to be either persistent, bio-accumulative and toxic (PBT), or very persistent and very bio-accumulative (vPvB) at levels of 0.1% or higher.
Acetic acid 50% – Hazards statements
H314 – Causes severe skin burns and eye damage.
H402 – Harmful to aquatic life.Precautionary statements
P260 – Do not breathe mist, vapors, spray.
P264 – Wash exposed skin thoroughly after handling.
P273 – Avoid release to the environment.
P280 – Wear protective gloves, eye protection.
P301 + P330 + P331 – If swallowed: rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 – If on skin (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305+P351+P338 – If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
Acetic acid 50% – Composition of Chemical
Chemical Formula: No Data Available
EC No 1272/2008: No Data Available
Acetic acid 50% – First Aid Measures
General Advice: Consult a physician. Show this safety data sheet to the doctor in attendance.
If: Inhaled: If breathed in, move person into fresh air. Allow the victim to rest. If not breathing, give artificial respiration. Consult a physician.
If: Skin Contact: Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Consult a physician.
If: Eye Contac: Rinse thoroughly with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Consult a physician.
If: Swallowed: Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician
Important Symptoms: The most important known symptoms and effects are described in the labeling section.
Immediate Medical Attention: No Data Available
Acetic acid 50% – Firefighting Measures
Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical or Carbon Dioxide.
Hazards Arising: Carbon Oxides
Advice for Firefighters: Wear self-contained breathing apparatus for firefighting if necessary
Info for Firefighting: Use water spray to cool unopened containers
Accidental Release MeasuresPersonal Precautions: Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation.
Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas.
Enviromental Precautions: Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
Method for Containment: Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations.
Acetic acid 50% – Handling and Storage
Personal Precautions: Avoid inhalation of vapour or mist.
Keep away from sources of ignition – No smoking.
Take measures to prevent the build up of electrostatic charge.
Enviromental Precautions: Store in cool place.
Keep container tightly closed in a dry and well-ventilated place.
Containers which are opened must be carefully resealed and kept upright to prevent leakage.
Moisture sensitive.
Storage class (TRGS 510): Flammable liquids
Exposure Controls | Personal Protection
Derived No Effect Level (DNEL)
Workers | Application Area | Exposure Routes | Health Effect | Value
Application Area Exposure routes Health effect Value
Workers Inhalation Acute local effects 25 mg/m3
Workers Inhalation Long-term local effects 25 mg/m3
Workers Skin contact Long-term local effects 10mg/kg BW/d
Consumers | Application Area | Exposure Routes | Health Effect | Value
Application Area Exposure routes Health effect Value
Consumers Inhalation Acute local effects 25 mg/m3
Consumers Inhalation Long-term local effects 25 mg/m3
Predicted No Effect Concentration (PNEC)
Compartment Value
Soil 0,478 mg/kg
Marine water 0,3058 mg/l
Fresh water 3,058 mg/l
Marine sediment 1,136 mg/kg
Fresh water sediment 11,36 mg/kg
Sewage treatment plant 85 mg/l
Aquatic intermittent release 30,58 mg/lEngineering Controls: Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday
Eye/Face Protection: Tightly fitting safety goggles. Face shield (8-inch minimum). Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166 (EU).
Skin Protection: Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove’s outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.
Full contact
Material: butyl-rubber.
Minimum layer thickness: 0,3 mm
Break through time: 480 min.
Material tested: Butoject®
Splash contact
Material: Nature latex/chloroprene.
Minimum layer thickness: 0,6 mm
Break through time: 32 min.
Material tested: Lapren®
Data source: KCL GmbH, D-36124. Test method: EN374
If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.
Body Protection: Complete suit protecting against chemicals. Flame retardant anti-static protective clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory Protection: Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multipurpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Physical and Chemical Properties
Appearance: Clear, Colourless liquid
Odour: Pungent
Odour Threshold: No Data Available
pH: No Data Available
Melting Point: Melting point/range: 4°CBoiling Point: 117 – 118°C at 1.013 hPa
Flash Point: 40°C – closed cup
Evaporation: No Data Available
Flammability: No Data Available
Upper/Lower Flammability or Explosive Limits: Upper explosion limit: 19.9% (V)
Lower explosion limit: 4% (V)
Vapour pressure: 15,2 hPa at 20°C
Vapour density: No Data Available
Relative density: No Data Available
Water solubility: Completely Miscible
Partition Coefficien: No Data Available
Auto-ignition Temperature: No Data Available
Decomposition Temperature: No Data Available
Viscosity: No Data Available
Explosive properties: No Data Available
Oxidizing properties: No Data Available
Other Safety Info: No Data Available
Stability and Reactivity
Reactivity: No Data Available
Chemical Stability: Stable under recommended storage conditions.
Possibility of hazardous reactions: No Data Available
Conditions to Avoid: Avoid moisture.
Avoid direct sunlight, heat, flames and sparks.
Incompatible Materials: Peroxides, Permanganates, e.g. Potassium Permanganate, Amines, Alcohols
Hazardous Decomposition Products: No Data Available
Toxicological Information
Acute Toxicity: LD50 Oral – Rat – 3.310 mg/kg.
Rat; Other; Read-across
Skin Corrosion/Irritation: Skin – Rabbit
Result: Severe burns
Serious Eye damage | Eye Irritation: Eyes – Rabbit Result: Corrosive to eyes
Cell Mutagenicity: No Data Available
Carcinogenicity: IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity: No Data Available
Specific Target Organ Toxicity – Single Exposure: No Data Available
Specific Target Organ Toxicity – Repeated Exposure: No Data Available
Aspiration Hazard: No Data Available
Ecological Information
Ecological Toxicity: Toxicity to fish: Semi-static test LC50 – Oncorhynchus Mykiss (rainbow trout) – > 1.000 mg/l – 96 h (OECD Test Guideline 203)
Toxicity to daphnia and other aquatic invertebrate: EC50 – Daphnia Magna (Water flea) – > 300,82 mg/l – 48 h (OECD Test Guideline 202)
Ecological Persistence and degradability: No Data Available
Bioaccumulative Potential: No Data Available
Mobility in Soil: No Data Available
Results of PBT and vPvB Assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Other Adverse Effect: No Data Available
Disposal Considerations
Waste Treatment Methods: Product:
Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company.
Contaminated packaging:
Dispose of as unused product.
Transport Information
UN Number: ADR/RID: 2790
IMDG: 2790
IATA: 2790UN Shipping Hazard: ADR/RID: Acetic Acid (solution)
IMDG: Acetic Acid (solution)
IATA: Acetic Acid (solution)
Transport Hazard Class: ADR/RID: 8
IMDG: 8
IATA: 8
Packaging Group: ADR/RID: II
IMDG: II
IATA: II
Enviromental Hazards: ADR/RID: no
IMDG Marine pollutant: no
IATA: no
Special Precautions: No Data Available
Regulatory Information
Safety, Health and environmental regulations: This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
Chemical Safety Assessment: A Chemical Safety Assessment has been carried out for this substance.
Additional Info: RTECS: Not available
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
Disclaimer
The information stated above is considered to be correct, but does not claim to be inclusive and shall only be used as a guideline. The information provided by this document is confirmed by our continuous updating of knowledge and adheres to the products appropriate safety precautions. It does not represent any guarantee of the product’s
properties. RLS Chemicals and its Associates shall not be held accountable for any damage’s consequent of handling the above product
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